A Reinvestigation of the Claim that Stannocene and h5-Cyclopentadienyltricarbonyltungsten Hydride Form Bis-(h5-cyclopentadienyltricarbonyltungsten) tin (II).

Abstract

Reinvestigation of the claim that stannocene and h5-cyclopentadienyltricarbonyltungsten hydrige form bis-(h5-cyclopentadienyltricarbonyltungsten) tin(II), the sole representative of a class of compounds in which tin(II) is attached to electropositive ligands, is revealed to be the facile halogenation product from the recrystallization fromhalocarbons of the tris-(h5-cyclopentadienyltricarbonyltungsten)tin(IV) hydride which actually results from the action of the stannocene on the tungsten hydride. The tris-(h5-cyclopentadienyltricarbonyltungsten)tin(IV) hydride, chloride, bromide and iodide are reported.

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Document Details

Document Type
Technical Report
Publication Date
Oct 15, 1980
Accession Number
ADA090779

Entities

People

  • C. D. Huff
  • J. W. Connolly
  • Jerold J. Zuckerman
  • T. S. Dory

Organizations

  • University of Oklahoma

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Halogenation
  • Magnetic Resonance
  • Mass Spectra
  • Mass Spectroscopy
  • Metals
  • Military Research
  • Molecular Weight
  • Nuclear Magnetic Resonance
  • Spectra
  • Spectroscopy
  • Tin
  • Transition Metals
  • Tungsten
  • United States

Fields of Study

  • Chemistry

Readers

  • Analytical Mechanics
  • Organic Chemistry