On the Photoassisted Hydrogen Production from Titania and Water.

Abstract

When TiO2, reduced by H2 or CO, is placed in an ambient of gas phase water and illuminated with band gap light, H2 is evolved. Adding a small amount of O2 completely retards this reaction. A dark reaction of reduced TiO2 with water to form H2 also occurs at temperatures above 200 C. These results show that H2 evolution is not the result of catalytic water photolysis but a photoassisted reaction of water with oxygen vacancies produced by the reduction. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Nov 12, 1980
Accession Number
ADA092223

Entities

People

  • J. Michael White
  • S. Sato

Organizations

  • University of Texas at Austin

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Band Gaps
  • California
  • Chemical Compounds
  • Chemistry
  • Compound Semiconductors
  • Energy Bands
  • Engineering
  • Hydrogen
  • Illinois
  • Materials
  • Materials Science
  • Military Research
  • New York
  • Pennsylvania
  • Physical Chemistry
  • Surface Chemistry
  • United States

Fields of Study

  • Materials science

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Environmental Engineering
  • Molecular Photonics/Laser Physics