Radiotracer Evaluation of the Contribution of Degradation Products of Phenolic Resins to the Poisoning of Electrodes in the 190 C Hydrogen/Air Fuel Cell.

Abstract

Improved procedures have been developed for the fabrication of powdered graphite/phenol-formaldehyde resin bipolar plates, which result in greatly improved resistance of the plates to attack by 190 C H3PO4. Static ageing tests of graphite-resin composites demonstrated that very low H3PO4 corrosion rates could be obtained and that essentially all plate etching occurred during the first 300 hours of test. Two miniature (2 in. x 2 in.) hydrogen-air fuel cells, with Carbon-14 labelled phenolic resin in the bipolar plates, were successfully operated for 1300 hours each. Post-operation radiochemical analysis showed no radioactivity present on the anode or cathode of either cell, thus indicating that phenolic degradation products could not have contributed to any electro-catalyst poisoning during these two runs.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1980
Accession Number
ADA096052

Entities

People

  • James T. Hoggins
  • Marvin L. Deviney

Tags

Communities of Interest

  • Advanced Electronics
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Cells
  • Chemical Synthesis
  • Chemistry
  • Composite Materials
  • Corrosion Resistance
  • Electrodes
  • Fossil Fuels
  • Fuel Cells
  • Graphitic Materials
  • Hydrogen Air Fuel Cells
  • Material Degradation Processes
  • Materials
  • Materials Science
  • Measurement
  • Phosphoric Acids
  • Physical Properties
  • Poisoning

Readers

  • Aquatic Ecology
  • Materials Science and Engineering.
  • Reinforced Composite Materials

Technology Areas

  • Biotechnology