Cathodic Electrochromism of Lutetium Diphthalocyanine Films.

Abstract

Cathodic electrochromism of lutetium diphthalocyanine films on insulating substrates was investigated by a moving-boundary technique. Reduction occurred by injection of electrons from a gold contact and cations from a liquid electrolyte. Light blue products formed with aqueous or organic solutions of alkali metal salts, while a dark violet product formed with aqueous hydrochloric acid. The dark material had a charge-carrier mobility of 8 times (ten to the minus 7th) cm squared/V-sec and an estimated bulk resistivity of 1,800 ohm-cm. Reduced forms of the dye appear to be solid cation conductors. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1981
Accession Number
ADA097009

Entities

People

  • F. A. Pizzarello
  • M. M. Nicholson

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkali Metals
  • California
  • Carrier Mobility
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Electric Fields
  • Elements
  • Hydrochloric Acid
  • Ionic Liquids
  • Liquids
  • Materials
  • Materials Science
  • Military Research
  • New York
  • Protons
  • Substrates

Readers

  • Forest Ecology
  • Semiconductor Device Technology
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene