An Investigation of Unique Metal Complexes Produced Using Polystyrene-2,2'-bipyridine as a Support, and Several Hydrogenation Catalysts Derived from this Copolymer,

Abstract

The cleavage reaction between polystyrene bound pyridine and 2,2'-bipyridine ligands, p-py and p-bipy, and the dimers (Rh(X)(CO)C1)2 (X=CO, (C6H5)3P, or toly13P) were studied. While the p-py cleavages produced products analogous to those found homogeneously, the reactions using p-bipy resulted in the formation of several metal complexes not found in solution. This is at least in part the result of the accessability of the initially formed p-bipy-rhodium complexes to subsequent reactions which cannot occur in the homogeneous case due to precipitation of the rhodium complex initially formed.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Mar 16, 1981
Accession Number
ADA097174

Entities

People

  • A. G. El A'mma
  • Eric D. Nyberg
  • Russell S. Drago

Organizations

  • University of Illinois Urbana–Champaign

Tags

DTIC Thesaurus Topics

  • Alkanes
  • Alkenes
  • Catalysts
  • Chemical Synthesis
  • Chemistry
  • Coordination Complexes
  • Copolymers
  • Dielectric Polymers
  • Hydrogenation
  • Infrared Spectra
  • Organic Chemistry
  • Polymers
  • Polystyrenes
  • Pyridines
  • Resins
  • Spectra
  • Two Dimensional

Readers

  • Electrochemical Surface Science
  • Polymer Science and Technology

Technology Areas

  • Microelectronics