Isolation of a Stable Binuclear Copper Complex Containing a Copper-Copper Bonded Unit. The X-Ray Structure Determination ((7,8,15,16,17,18,25,26,33,34,35,36-Dodecahydrotetrabenzo(e,m,s,a')(1,4,8,11,15,18,22,25)Octa-Azacyclo-Octaeicosine)Dicopper) Triperchlorate.
Abstract
An octa-azamacrocycle with a 28-membered ring has been found to be capable of incorporating a symmetrical copper-copper bonded unit which contains a short Cu-Cu bond (2.445(4) A). The compound is paramagnetic with mu eff = 1.87 muB at 300 K and exhibits single lines at g = 2.09 in the X-band EPR spectra of solid samples or of frozen acetonitrile solutions (77 K). (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 15, 1980
- Accession Number
- ADA098244
Entities
People
- D. C. Brower
- K. P. Dancey
- P. A. Tasker
- R. Price
- W. E. Hatfield
Organizations
- University of North Carolina at Chapel Hill