1H and 13C Fourier Transform NMR Characterization of Jet Fuels Derived from Alternate Energy Sources.

Abstract

This report discusses LC-superscript 1H NMR studies from semi-preparative to analytical column size in order to establish ultimate chromatographic resolution conditions. It explores quantitative approaches for LC-superscript 1H NMR including a dual effluent stream to allow introduction of a quantitative reference before the superscript 1H NMR detector. It explores quantitative and ultimate sensitivity limits for the present superscript 1H NMR LC detector including optimization of superscript 1H NMR insert for LC-superscript 1H NMR. The report provides LC-superscript 1H NMR data profiles for 10 synthetic mixtures and corresponding analytical data (e.g., total %H, %H, aromatic, %H aliphatic, %n-alkanes and branched alkanes, %alkyl aromatics and substituted naphthalenes). LC-superscript 1H NMR data profiles for 30 middle distillate fuels and corresponding analytical data is provided. This report provides static superscript 1H NMR and superscript 13C NMR quantitative data for 45 middle distillate fuels. At least six of these samples will be diesel fuel marine. It also provides static superscript 1H NMR and superscript 13C NMR quantitative data for 20 synthetic mixtures of hydrocarbons.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1980
Accession Number
ADA098305

Entities

People

  • H. C. Dorn

Organizations

  • Virginia Tech

Tags

DTIC Thesaurus Topics

  • Alkanes
  • Coefficients
  • Detectors
  • Diesel Fuels
  • Equations
  • Fuels
  • Hydrocarbons
  • Hydrogen
  • Jet Engine Fuels
  • Liquid Chromatography
  • Magnetic Resonance
  • Measurement
  • Military Research
  • Mixtures
  • Naphthalenes
  • Nuclear Magnetic Resonance
  • Octadecanes

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Organic Chemistry
  • Petroleum Engineering