Experimental and Theoretical Study of the Feasibility of the Gunn Effect in BiSCl, BiSBr, BiSI, BiSeI, BiSeBr and BiSeCl.

Abstract

The optical reflectance of BiSI has been measured with photon energy, from 2.2 to 3.6 eV. The band structures of BiSBr, BiSCl, BiSeBr, BiSeCl and BiSeI have been calculated by using the self-consistent pseudopotential method. These results show that: (i) they are indirect gap semiconductors; (ii) the top of the valence band is located at some k-point along rZ (the z-direction) with finite curvature (small effective mass); (iii) the highest valence band at r (the center of the Brillouin zone) is only a few tenths of an eV lower than the energy of the top of the valence band and is flat (large effective mass) especially in the directions perpendicular to z. (iv) in addition to the above listed features, the minimum of the conduction band for BiSCl and BiSeCl is located at some k-point along rX, the x direction and is a few tenths of an eV lower than the lowest conduction band at r. These results suggest that: All the six compounds studied in this project will exhibit the Gunn effect if they are properly doped. They are potential candidates for microwave oscillators. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1981
Accession Number
ADA099180

Entities

People

  • C Fong Y.
  • F. Wooten

Organizations

  • University of California, Davis

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Band Structures
  • Brillouin Zones
  • Charge Density
  • Conduction Bands
  • Curvature
  • Electric Fields
  • Electrons
  • Energy Bands
  • Gunn Effect
  • Measurement
  • Microwave Oscillators
  • Nuclear Energy
  • Optical Detectors
  • Scientific Research
  • Semiconductors
  • Valence Bands

Fields of Study

  • Materials science

Readers

  • Ballistic Missile Meteorology
  • Quantum Chemistry
  • Spectroscopy.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene