Electrochemical Behavior of Sulfide at the Silver Rotating Disc Electrode. II. Mechanism of Silver Film Formation.

Abstract

Steady state anodic voltammograms were measured at a silver rotating disc electrode in a basic sulfide solution. Analysis of the voltammograms indicates that the rate determining steps in the dissolution of silver are due to a combination of surface chemical reaction, forming silver sulfide, and the charge transfer-reaction between silver and silver ion. Kinetic parameters of each step are evaluated and an I-E curve is reproduced from these parameters. The wave form is in good agreement with the voltammogram obtained experimentally. (Author)

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1981
Accession Number
ADA099226

Entities

People

  • Koichi Aoki
  • Kunio Shimizu
  • Robert A. Osteryoung

Organizations

  • University at Buffalo

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Communities of Interest

  • Advanced Electronics
  • Air Platforms
  • C4I
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Arrhenius Equation
  • Boltzmann Equation
  • Charge Transfer
  • Chemical Engineering
  • Chemical Reactions
  • Chemistry
  • Electrodes
  • Energy
  • Equations
  • Materials
  • Materials Science
  • Military Research
  • New York
  • Rate Of Formation
  • Surface Reactions
  • United States
  • Universities

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  • Electrochemical Surface Science