The Synthesis and Characterization of 1,1-(P(C6H5)3)2-1-H-1,2,4-RhC2B10H12: A Supraicosahedral Metallocarborane Catalyst Precursor.

Abstract

The 13-vertex supraicosahedral metallocarborane 1,1-(P(C6H5)3)2-1-H-1,2,4-RhC(2)B(10)H(12), a hydrogenation catalyst precursor, has been synthesized through routes analogous to 10-,11-, and 12-vertex phosphinorhodacarborane formation, and characterized by NMR studies and an X-ray diffraction crystal structure analysis. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Feb 04, 1981
Accession Number
ADA099417

Entities

People

  • Carolyn B. Knobler
  • John D. Hewes
  • M. Frederick Hawthorne

Organizations

  • University of California, Los Angeles

Tags

Communities of Interest

  • Air Platforms
  • Ground and Sea Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • California
  • Catalysts
  • Chemistry
  • Crystal Structure
  • Crystals
  • Diffraction
  • Hydrogenation
  • Massachusetts
  • Military Research
  • New York
  • North Carolina
  • Oklahoma
  • Pennsylvania
  • United States
  • Virginia
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry