Oxotrimolybdenum (IV) Alkoxides: Mo3(micron 3-O)(micron 3-OR)(micron 2-OR)3(OR)6, Where R = i-Pr and CH2CMe3 - from Serendipitous Discovery to Total Synthesis.

Abstract

Oxotrimolybdenum(IV) alkoxides, Mo30(OR)10 where R = isopropyl and nepoentyl, have been discovered and are shown to be related to a rapidly emerging class of triangulo early transition metal complexes recently reported by Cotton and coworkers. A high yield synthesis of the new compounds is described and involves the addition of an oxomolybdenum(6+) unit across a Mo Triple Bond Mo bond. (Author)

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Document Details

Document Type
Technical Report
Publication Date
May 18, 1981
Accession Number
ADA099647

Entities

People

  • C. C. Kirkpatrick
  • J. C. Huffman
  • K. Folting
  • M. H. Chisholm

Organizations

  • Indiana University

Tags

DTIC Thesaurus Topics

  • Abstracts
  • Chemistry
  • Coordination Complexes
  • Elements
  • Governments
  • Metals
  • Military Research
  • Molecular Structure
  • Molybdenum
  • Security
  • Transition Metals
  • United States
  • United States Government
  • Universities
  • X Rays

Fields of Study

  • Chemistry

Readers

  • Educational Psychology
  • Organic Chemistry