Examination of Errors in the Determination of Phase Boundary Thickness by Small Angle X-ray Scattering.

Abstract

The method of determining the thickness of diffuse phase boundary with density profile governed by equilibrium conditions is proposed. It follows the well-known procedure of analyzing the deviations from Porod's law. Errors in the obtained boundary thickness, due to statistical scatter in the intensity data and to the difficulty of separating the effect of density fluctuations within the phases, are examined. For this purpose, scattering curves are synthesized on the basis of a well-defined model structure with known boundary thicknesses. These synthesized curves, when analyzed according to the proposed method, yield the correct boundary thickness under favorable conditions, but are also shown to lead to very erroneous results in some cases. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jun 10, 1981
Accession Number
ADA100418

Entities

People

  • Ryong-joon Roe

Organizations

  • University of Cincinnati

Tags

Communities of Interest

  • Cyber
  • Weapons Technologies

DTIC Thesaurus Topics

  • Block Copolymers
  • Chemical Engineering
  • Chemistry
  • Copolymers
  • Electron Density
  • Electrons
  • Engineering
  • Geometry
  • Materials
  • Materials Laboratories
  • Materials Science
  • Military Research
  • Polymers
  • Scattering
  • Transition Temperature
  • X Ray Scattering
  • X Rays

Readers

  • Electromagnetic Wave Scattering and Antenna Radiation Engineering
  • Materials Science and Engineering.
  • Regression Analysis.