Research on HgCdTe Fabrication Using Directed Energy Techniques

Abstract

The goal of this research is to produce large-area, thin-film, single crystal HgCdTe material for infrared detectors. The successful approach is to (1) evaporate CdTe in an enclosed furnace on insulating crystalline substrates (hot wall epitaxy), (2) melt a thin surficial layer by pulsed electron beam irradiation to improve morphology, and (3) convert to HgCdTe by evaporation and diffusion at constant temperature. The final result is a single crystal film of Hg(1-x)CdxTe, 30 microns thick and 0.5 inch square, with a compositional variation of x less than + or - 0.0007. Films of up to 20 microns thick, 1 inch o.d., single crystal (but twinned) CdTe were produced by the first process. These faceted films were smoothed without change of surface stoichiometry or structure by the second process. Evaporation of HgTe at less 0.5 atm Hg overpressure onto the CdTe film produced the final result on mica or quartz substrates. Electron mobility at 77 K was as high as 1.5 x 100,000 sq cm/V-s in the final samples.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1981
Accession Number
ADA101240

Entities

People

  • Anton C. Greenwald
  • Robert G. Wolfson

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Crystal Structure
  • Crystals
  • Diffraction
  • Electrical Properties
  • Electron Beams
  • Electron Mobility
  • Electrons
  • Epitaxial Growth
  • Films
  • Heat Energy
  • Materials
  • Measurement
  • Phase Diagrams
  • Polycrystals
  • Single Crystals
  • Thin Films
  • Vapor Pressure

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene