Analytical Method for Concentration of Trace Organics from Water

Abstract

An efficient and rapid method is described for the concentration of trace organics from water. The compounds tested were chosen from the primary and secondary products of the microbial transformation of 2,4,6-trinitrotoluene (TNT). The four compounds covered a range of polarities (2,4-diamino-6- nitrotoluene, TNT, 2-amino-4,6-dinitrotoluene and 2,2',6,6'-tetranitro-4,4'- azoxytoluene) and were tested at concentrations down to 1 ppb. Solutions were extracted with SEP-PAK C-18 cartridges (Water Assoc.) and quantitized by high performance liquid chromatography. Efficient recoveries were obtained for three compounds while the most polar compound, 2,4-diamino-6-nitrotoluene, showed low recovery. Amounts down to 30 ng were routinely detected.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1981
Accession Number
ADA101639

Entities

People

  • A. M. Kaplan
  • D. L. Kaplan

Organizations

  • United States Army Soldier Systems Center

Tags

Communities of Interest

  • Biomedical
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alcohols
  • Chromatography
  • Detection
  • Environmental Monitoring
  • Environmental Protection
  • Explosives
  • Liquid Chromatography
  • Materials
  • Methanols
  • Monitoring
  • Nitrotoluenes
  • Organic Compounds
  • Public Health
  • Solvent Extraction
  • Standards
  • Technology Transfer
  • Tnt

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Organic Chemistry

Technology Areas

  • Biotechnology
  • Biotechnology - Bioremediation