Time-of-Flight Spectroscopy of Molecular Structure, Collision Processes, and Gas-Surface Interactions.

Abstract

Progress is reported on research in molecular physics involving electron-bombardment molecular dissociation. The velocity distribution of metastable and ionic fragments are measured using a pulsed electron beam and a time-of-flight technique. Fragments from the hydrogen molecule and its deuterated forms have been investigated using electron energies from 30 to 100 electron-volts. Dissociation channels via particular molecular or molecular ion excited states have been proposed to explain observed features in the velocity spectra. A similar experiment involving hydrogen fragments from the hydrogen halides is also in progress. Preliminary data show several resolved velocity groups indicating the presence of multiple dissociating channels. Experiments using water and hydrogen sulfide molecules are also underway. Finally, we are continuing to develop our ion mass filter which allows us to obtain separate ion velocity distributions for each mass in a situation in which several ion masses are present. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jul 15, 1981
Accession Number
ADA105438

Entities

People

  • Laurence C. Mcintyre Jr
  • Willis E. Lamb Jr.

Organizations

  • University of Arizona

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Air Force
  • Chemical Engineering
  • Chemistry
  • Dissociation
  • Electron Beams
  • Electron Energy
  • Electron Guns
  • Electrons
  • Energy
  • Gas Surface Interactions
  • Kinetic Energy
  • Molecular Physics
  • Molecular Structure
  • Molecules
  • Physical Chemistry
  • Physics
  • United States

Fields of Study

  • Chemistry
  • Physics

Readers

  • Molecular Photonics/Laser Physics

Technology Areas

  • Directed Energy
  • Microelectronics