Lithium Based Anodes for Solid State Batteries

Abstract

The work of the two previous reports is reviewed and the last year's work is reported in detail. The latter involved the use of 'staircase wave cyclic voltammetry,' a technique designed to characterize the transport properties of an electrode material over a wide composition range. This technique was applied to the compounds Fex, Si, a glassy metal of composition (Fe95Si7)B15, and a newly found prospective negative plate material HgxLi. An analysis of composite electrodes - those containing an additional ionic conductor, e.g. a solid electrolyte, as the grain boundary phase of the charge storage material shows that the criteria initially applied to the selection of an electrode may be significantly relaxed. Experiments with the composite of lithium-aluminum alloy with the solid electrolyte polyethylene oxide-lithium trifluoromethane sulphonate have verified the analysis which can be applied to many more systems.

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Document Details

Document Type
Technical Report
Publication Date
Jun 30, 1981
Accession Number
ADA105518

Entities

People

  • B. C. Steele
  • J. R. Owen
  • R. A. Edwards

Organizations

  • Imperial College London

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alloys
  • Aluminum Alloys
  • Chemistry
  • Composite Materials
  • Diffusion Coefficient
  • Electrodes
  • Figure Of Merit
  • Grain Boundaries
  • Grain Size
  • Ionic Liquids
  • Lithium Compounds
  • Materials
  • Materials Processing
  • Materials Science
  • Materials Testing
  • Particle Size
  • Particles

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Forest Ecology
  • Semiconductor Device Technology