HgCdTe Fabrication Using Directed Energy Techniques

Abstract

The goal of this research is to produce large-area, thin-film, single crystal mercury cadmium telluride material for infrared detectors. The successful approach is to (1) evaporate cadmium telluride in an enclosed furnace on insulating crystalline substrates (hot wall epitaxy), (2) melt a thin surficial layer by pulsed electron beam irradiation to improve morphology, and (3) convert to mercury cadmium telluride by evaporation and diffusion at constant temperature. The final result is a single crystal film of Hg (sub 1-x) Cd sub x Te, 30 microns thick and 0.5 inch square, with a compositional variation of x less than + or - 0.0007. Films of up to 20 microns thick, 1 inch o.d., single crystal (but twinned) CdTe were produced by the first process. These faceted films were smoothed without change of surface stoichiometry or structure by the second process. Evaporation of HgTe at less 0.5 atm Hg overpressure onto the CdTe film produced the final result on mica or quartz substrates. Electron mobility at 77 K was as high as 1.5 x 10 to the 5th power sq cm/V-s in the final samples.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1981
Accession Number
ADA105626

Entities

People

  • Anton C. Greenwald
  • Robert G. Wolfson

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Compound Semiconductors
  • Crystal Growth
  • Crystal Structure
  • Crystal Twinning
  • Crystals
  • Diffraction
  • Directed Energy Weapons
  • Electron Mobility
  • Epitaxial Growth
  • Heat Energy
  • Materials Processing
  • Measurement
  • Phase Diagrams
  • Spectra
  • Spectroscopy
  • Thin Films
  • Transition Temperature

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Semiconductor Device Technology

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene