Crystal and Molecular Structure of Mo6O10(OPr(i))12: A Serpentine Chain of Molybdenum Atoms and Observation of Semibridging Alkoxy Ligands.

Abstract

Mo6O10(OPr(1)12, an intermediate in the reaction between Mo2 (OPr(1))6 and molecular oxygen which yields (MoO2(OPr(1))2)n, has been structurally characterized and found to contain a serpentine chain of molybdenum atoms connected by bridging oxo and alkoxy ligands; there is also a pair of alkoxy ligands which are semibridging. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Oct 14, 1981
Accession Number
ADA105769

Entities

People

  • Charles C. Kirkpatrick
  • John C. Huffman
  • Kirsten Folting
  • Malcolm H. Chisholm

Organizations

  • Indiana University

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  • Air Platforms

DTIC Thesaurus Topics

  • Chemistry
  • Governments
  • Metal Metal Bonds
  • Metals
  • Military Research
  • Molecular Orbital Theory
  • Molecular Structure
  • Molecules
  • Molybdenum
  • New York
  • Observation
  • Radiation
  • Terminals
  • United States
  • United States Government
  • Universities

Fields of Study

  • Chemistry

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  • Organic Chemistry