Reductions in Aprotic Media II. Influence of Catalytic Hydrogen Reduction on the Course of Hydrocarbon Reduction.

Abstract

The reduction of polycyclic aromatic hydrocarbons at platinum electrodes in aprotic solvents does not normally occur before surface hydrogen is reduced. The reduced hydrogen reacts with the hydrocarbon before the anion radical can be formed. The intermediate species formed after electron transfer are easily observed at very low concentrations by using modulated specular reflectance spectroscopy (MSRS). (Author)

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1981
Accession Number
ADA106232

Entities

People

  • B. Stanley Pons
  • S. B. Khoo

Organizations

  • University of Alberta

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Aromatic Hydrocarbons
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Crystal Lattices
  • Cyclic Hydrocarbons
  • Dielectric Gases
  • Electrochemistry
  • Electron Transfer
  • Materials
  • Materials Laboratories
  • Materials Science
  • Military Research
  • New York
  • Spectra
  • Voltammetry
  • Waveform Generators

Fields of Study

  • Chemistry
  • Environmental science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies

Technology Areas

  • Microelectronics