Long Range Materials Research. Appendix 1. Synthesis and Characterization of Supported Organometallic Rhodium (I) Catalysts

Abstract

This thesis deals with the continuing effort to chemically bind well defined homogeneous organometallic catalysts on the surface of the inert support and to study their behavior. The work has shown that a chelating bisphosphine ligand (2-(3-triethoxysilylpropyl)-1,3-bis(diphenylphosphino)propane) can effectively support and immobilize an organometallic Rh(I) hydrogenation catalyst on a silica surface. Through a series of tests, this bound hydrogenation catalyst behaves in a manner expected of an analog of homogeneous organometallic Rh(I) catalysts and not like a metallic rhodium catalyst.

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Document Details

Document Type
Technical Report
Publication Date
Jun 30, 1974
Accession Number
ADA109465

Entities

People

  • Donald Nilan Marquardt

Organizations

  • Stanford University

Tags

Communities of Interest

  • Advanced Electronics
  • C4I

DTIC Thesaurus Topics

  • Alkanes
  • Alkenes
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Crystals
  • Dielectric Gases
  • Electron Microscopy
  • Materials
  • Materials Processing
  • Materials Science
  • Metal Crystals
  • Organic Chemistry
  • Plastic Explosives
  • Silicon Dioxide

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Systems Analysis and Design