Quantum Model of Selective Multiphoton Processes: The Role of External (Field) and Internal (Anharmonic Coupling) Detunings.
Abstract
Quantum equations of motion describing the energy transfer dynamics via intramolecular anharmonic coupling are presented and solved numerically. Dynamical features of the average excitations of a homogeneous system (SF6) and a heterogeneous system (H/W) are quantitatively discussed in terms of the intramolecular vibrational relaxation (IVR) rates. Possible mechanisms of surface-enhanced desorption via low-power laser radiation are proposed. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1982
- Accession Number
- ADA111215
Entities
People
- Jui-teng Lin
- Thomas F. George
Organizations
- University of Rochester