Uptake and Fate of Tri-N-Butyltin Cation in Estuarine Bacteria,

Abstract

The uptake and possible metabolic transformation of tri-n-butyltin cation by tin-resistant estuarine bacteria was studied. The bacterial isolates accumulated tributyltin to 3.7 to 7.7 mg tin per g dry weight of cells by a non-energy requiring process, probably by adsorption to the cell envelope. Chemical speciation of cell extracts and culture media by combined liquid chromatography-atomic absorption spectrophotometry and tin-selective purge and trap flame photometric gas chromatography for possible tributyltin degradation products revealed no significant biotransformations of tributyltin cation by the tributyltin-resistant isolates. Apparently the isolates accumulate, but do not metabolize, tributyltin. Research into the persistence of tributyltin cation in natural estuarine waters and sediments is needed. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Apr 02, 1982
Accession Number
ADA113526

Entities

People

  • F. E. Brinckman
  • G. J. Olson
  • W. P. Iverson
  • W. R. Blair

Organizations

  • National Institute of Standards and Technology

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Bacteria
  • Biodegradation
  • Cells
  • Cellular Structures
  • Chemical Analysis
  • Chemical Speciation
  • Chemical Synthesis
  • Chemistry
  • Chesapeake Bay
  • Chromatography
  • Culture Media
  • Liquid Chromatography
  • Materials
  • Materials Science
  • Microbiology
  • Microorganisms
  • Organometallic Compounds

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Microbial Pathology