Fluoropolymer Barriers to Stress Corrosion in Optical Fibers

Abstract

Organic polymer coatings play a critical role in determining the overall performance of optical fibers. They protect the very fine silica glass core from abrasive damage and environmental effects such as stress induced corrosion. In addition they act as a buffer in reducing the sensitivity of the optical fiber to microbending loss. In designing a coating system for optical fibers it is necessary to strike a balance between two factors: a soft compliant enclosure that acts as a buffer in masking the nonuniform surface of the glass and a hard enclosure to act as a stiffener and make the fiber resistant to the environmental surface. These requirements are best suited by using a photocured polyfluoropolyolacrylate of reduced crosslink density as a primary coating and the high modulus fluoroepoxy resin as a secondary coating. Although it is possible to lower the glass transition and modulus of the fluoroepoxy system, the longer cure times required for heat curing systems, make them less attractive as a primary coating. Also the superior surface properties of the fluoroepoxy suggest themselves for use as an external coating.

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Document Details

Document Type
Technical Report
Publication Date
Jun 18, 1982
Accession Number
ADA117346

Entities

People

  • Liliana Klinger

Organizations

  • United States Army Communications-Electronics Command

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Corrosion
  • Fibers
  • Fluoropolymers
  • Glass
  • Glass Fibers
  • Glass Transition Temperature
  • Halogens
  • Material Degradation Processes
  • Materials Laboratories
  • Optical Fibers
  • Polymeric Films
  • Polymers
  • Resins
  • Stress Corrosion
  • Surface Properties
  • Surface Tension
  • Transition Temperature

Fields of Study

  • Materials science
  • Physics

Readers

  • Optical Fiber Sensing and Electromagnetic Propagation.
  • Reinforced Composite Materials
  • Surface Coatings Technology.