Kinetics of Hydrogen-Oxygen and Hydrocarbon-Oxygen Reactions.

Abstract

Rate constants of the H2 + 02 reaction at 500 C hae been refined. Rate constants and Arrhenius parameters for reactions of H atoms and OH radicals with C2-C5 alkanes, 2,2,3,3-tetramethylbutane (TMB) and 2,2,3-trimethylbutane (TRIMB) have been obtained. Detailed studies have been made of the products from the oxidation of 1-butane, n-pentane, neopentane, TMB and TRIMB. Rate constants for R + 02 = conjugate alkene, for homolysis of R Radicals, and for the isomerisation of R02 radicals to hydroperoxyalkyl radicals have been tabulated for a range of radicals.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1981
Accession Number
ADA118540

Entities

People

  • Raymond W. Walker
  • Robert R. Baldwin

Organizations

  • University of Hull

Tags

Communities of Interest

  • C4I
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Air Force
  • Aldehydes
  • Alkanes
  • Alkenes
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Decomposition
  • Dielectric Gases
  • Differential Equations
  • Dissociation
  • Organic Chemistry
  • Oxidation
  • Plastic Explosives
  • Rate Of Formation

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry