Role of Amines in Adhesion of Polybutadiene to Glass Substrates. IV. The Effect of Amine Structure and Concentration on the Strength of Adhesion.

Abstract

An attempt to elucidate the role of amines in general, and of 3-amino-propyltriethoxysilane in particular, has been made through a study of the title subject by several different approaches. This paper describes the effect of amine structure and concentration on the strength of adhesion of peroxide cured polybutadiene to a glass surface. It demonstrates that adhesion of polybutadiene to glass surfaces is enhanced by incorporation of small amounts of amines into the elastomer. An 80-fold increase in the work of adhesion was observed in the presence of 3-aminopropyltrimethyoxysilane. The results are interpreted in terms of information reported in previous papers in this series.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1982
Accession Number
ADA121686

Entities

People

  • Patricia Dreyfuss
  • Y. Eckstein

Organizations

  • University of Akron

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Adhesion
  • Air Force
  • Alkenes
  • Chemical Bonds
  • Chemical Engineering
  • Chemical Synthesis
  • Chemistry
  • Elastomers
  • Engineering
  • Equations
  • Materials
  • Mechanical Properties
  • Military Research
  • Molecular Orbital Theory
  • Physical Properties
  • Synthetic Rubber
  • United States

Readers

  • Organic Chemistry
  • Surface Coatings Technology.
  • Systems Analysis and Design