Vinyloxychloro-cyclotriphosphazenes.
Abstract
The reactions of the lithium enolate the acetaldehyde, LiOCHCH2, with hexachlorocyclotriphosphazene, N3P3Cl6, lead to the series of vinyloxychlorocyclotriphosphazenes, N3P3Cl6-n (OCH=CH2)n (n = 1-6). Evidence for the occurrence of all possible geometrical and positional isomers in the series has been obtained from the 31P nmr spectra. The principal products are the non-geminal species with comparable amounts of cis and trans isomers being formed. Small amounts of the geminal isomers also observed. The mono- and pentakis substituted derivatives have been converted to their dimethylamino derivatives, N3P3(OCH=CH2)6-n(N(CH3)2)n (n = 1,5). (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 06, 1982
- Accession Number
- ADA122598
Entities
People
- Christopher W. Allen
- Kolikkara Ramachandran
Organizations
- University of Vermont