Thermodynamics of Organic Compounds

Abstract

This research program consisted of an integrated and interrelated effort of basic and applied research in chemical thermodynamics and thermochemistry. Knowledge of variation of physical and thermodynamic properties with molecular structure was used to select compounds for study that because of high ring strain or unusual steric effects may have good energy characteristics per unit volume or per unit mass and thus be useful in the synthesis of high energy fuels. These materials were synthesized, and their thermodynamic properties were evaluated. In cooperation with researcher at Wright-Patterson Air Force Base, ramjet fuels currently in use were subjected to careful thermodynamic evaluation by measurements of heat capacity, enthalpy of combustion and vapor pressure. During the last year of this effort, seven kerosene-type fuels produced by British Petroleum and seven jet fuels produced from shale oil were studied. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1982
Accession Number
ADA125022

Entities

People

  • B. E. Gammon
  • N. K. Smith

Organizations

  • United States Department of Energy

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Facilities
  • Chemistry
  • Combustion
  • Enthalpy
  • Heat Capacity
  • Jet Propulsion
  • Materials
  • Measurement
  • Military Research
  • Organic Compounds
  • Shale Oil
  • Thermochemistry
  • Thermodynamic Properties
  • Thermodynamics
  • United States
  • Vapor Pressure

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Petroleum Engineering
  • Technical Research and Report Writing.