A Microscopic Model for the Liquid Metal - Ionic Solution Interface.
Abstract
A microscopic model for the metal-solution interface is presented, which for the first time, includes both a non-ideal treatment of the metal and a molecular model for the solution side. The metal is described by a jellium including electron-ion-pseudopotential. The solution is treated as a mixture of hard spheres with point dipoles (solvent molecules) or point charges (ions). The statistical mechanics is solved using the mean spherical approximation. No a priori separation is introduced between compact and diffuse layers. A simplified version of the model is applied to the case of Hg-DMSO systems. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Feb 10, 1983
- Accession Number
- ADA125531
Entities
People
- F. Vericat
- J. P. Badiali
- Lesser Blum
- M. L. Rosinberg
Organizations
- University of Puerto Rico