Interface States and Electron Spin Resonance Centers in Thermally Oxidized (111) and (100) Silicon Wafers

Abstract

Interface states and electron spin resonance centers have been observed and compared in thermally oxidized (111) and (100) silicon wafers subjected to various processing treatments. The ESR P sub b signal, previously assigned to interface Si---Si3 defects on (111) wafers, was found to have two components on (100): an Si---Si2O. The quantitative proportionality of P sub b spin concentration to midgap interface trap density D sub it is maintained on (100), and both are lower by a factor of about 3 compared to (111). This correlation persists over the range of oxidation temperatures 800-1200 deg C, for both n- and p-doped silicon, cooled by fast pull in oxygen, and cooled or annealed in nitrogen or argon. The correlation is independent of doping level. In samples with different oxide thickness, neither P sub b nor D sub it varied significantly over the range 100-2000 A, but P sub b was smaller at 50 A. In general, ESR is judged to offer promise for further studies of specific interface features.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1981
Accession Number
ADA126719

Entities

People

  • Bruce E. Deal
  • Edward H. Poindexter
  • Philip J. Caplan
  • Reda R. Razouk

Tags

DTIC Thesaurus Topics

  • Anisotropy
  • Annealing
  • Charge Density
  • Chemistry
  • Crystal Structure
  • Crystals
  • Electron Spin Resonance
  • Materials
  • Measurement
  • Metal Oxide Semiconductors
  • Oxidation
  • Oxides
  • Oxygen
  • Resonance
  • Semiconductors
  • Silicon Dioxide
  • Spin Resonance

Readers

  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Semiconductor Device Technology
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene