Fatigue Crack Growth and Surface Reactions for Titanium Alloys Exposed to Water Vapor.

Abstract

Parallel fracture mechanics and surface chemistry studies have been carried out to develop understanding of environmentally assisted fatigue crack growth in titanium alloys. Room temperature crack growth response in water vapor was determined for annealed Ti-5A1-2.5Sn alloy and for Ti-6A1-4V alloy in the solution treated and solution treated plus over-aged conditions as a function of water vapor pressure from 0.266 to 665 Pa at a frequency of 5 Hz and a load ratio of 0.1. Reference data were obtained in vacuum. The kinetics of reactions of water vapor and oxygen with fresh surfaces of Ti-5A1-2.5Sn alloy were measured at room temperature. The results showed that the reactions with water vapor and with oxygen are both rapid; with an initial sticking coefficient of 1.0 for water vapor and of 0.54 to 0.84 for oxygen. The reaction with water vapor produced a monolayer of oxide (TiO), whereas 2 to 3 layers of TiO resulted from the reaction with oxygen.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1983
Accession Number
ADA127328

Entities

People

  • G. W. Simmons
  • Robert P. Wei
  • S. J. Gao

Organizations

  • Lehigh University

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Auger Electrons
  • Chemical Compounds
  • Chemistry
  • Engineering
  • Heat Treatment
  • Materials
  • Materials Laboratories
  • Materials Science
  • Measurement
  • Mechanical Engineering
  • Mechanics
  • Metals
  • Military Research
  • Mining Engineering
  • Physics Laboratories
  • Spectra
  • Surface Chemistry

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science (Mechanical Engineering).
  • Powder metallurgy of Titanium alloys.