Reaction of Photochemically Generated Organic Cations with Colloidal Clays.

Abstract

Organic radical cations will dimerize when adsorbed to the surface of montmorillonite in colloidal solution. This dimerization is primarily the result of a concentration effect and the ability of organic probes to colonize or sequester on the clay particle surface or within its layers. The adsorption of organic cations to the clay surface is primarily a cation exchange process. The rate constant for cation exchange is 3.25 x 10 to the 6th power L/equivalents sec.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1983
Accession Number
ADA127506

Entities

People

  • Louis Joseph Kovar

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Acids
  • Alcohols
  • Chemical Products
  • Chemical Reactants
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Electron Paramagnetic Resonance
  • Organic Materials
  • Paramagnetic Resonance
  • Spectra
  • Spectroscopy
  • United States Military Academy

Readers

  • Agricultural Chemistry/Soil Science
  • Organic Chemistry