An Investigation of the Presence of N,N'-Bis(2,4,6-Trichlorophenyl)urea in Estuarine Sediments of Aberdeen Proving Ground, Maryland (Edgewood Area).

Abstract

N,N' -Bis(2,4,6-trichlorophenyl)urea is present in the sediments of Canal Creek in the Edgewood area of Aberdeen Proving Ground, MD. The highest concentrations are found in the top 2 inches of sediment, (100-300 micrograms/g), and the concentration declines with increasing depth. Below a 6-inch depth there is little of no contamination. Although the detection limit of the HPLC method descrived here is 5 micrograms of dry sediment, modification of this method to lower levels is possible. The chemical literature gives little information concerning this material, but does indicate a very high stability to chemical hydrolysis. The solubility in water is quite low (82 microgram at 22 degrees) and the estimted octanol/water partition coefficient is high (log K >5). The conjunction of these properties points to long persistence of the compound in the environment.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1983
Accession Number
ADA129731

Entities

People

  • William H. Dennis Jr.

Organizations

  • United States Army Medical Research and Development Command

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DTIC Thesaurus Topics

  • Acetonitrile
  • Alcohols
  • Chemical Analysis
  • Chemical Synthesis
  • Chemistry
  • Detection
  • Detectors
  • Liquid Chromatography
  • Literature Surveys
  • Mass Spectra
  • Materials
  • Measurement
  • Nitriles
  • Organic Compounds
  • Phase
  • Spectra
  • Spectrometers

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  • Agricultural Chemistry/Soil Science
  • Environmental Engineering
  • Military/Explosive Ordnance Disposal (EOD) Technology