Preparation of HI-6, HGG-12 and Toxogonin.

Abstract

Published procedures for synthesis of HI-6 result in a difficult-to handle intermediate, and a product contaminated with symmetrical impurities. Because of these comtaminants, purification requires repeated recrystallizations and leads to substantial material losses. We have discovered two methods that result in acceptable quality HI-6. Neither of these methods is optimized, however, and overall yields are low. We currently have 1150 g of 85% pure HI-6, prepared according to Good Manufacturing Practices (GMP). The preparation of Toxogonin is much easier than that of HI-6 because the former is symmetrical. We have 680 g of 99% pure and 400 g of 94% pure Toxogonin prepared according to GMP.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1983
Accession Number
ADA132484

Entities

People

  • M. A. Geigel
  • M. M. Broussard

Organizations

  • SRI International

Tags

DTIC Thesaurus Topics

  • Alcohols
  • Chromatography
  • Classification
  • Construction Materials
  • Diesel Fuels
  • Elements
  • Health
  • High Pressure
  • Ion Exchange
  • Liquid Chromatography
  • Magnetic Resonance
  • Materials
  • Methanols
  • Nuclear Magnetic Resonance
  • Organic Solvents
  • Security
  • Silica Gels

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  • Analytical Chemistry
  • Materials Science and Engineering.
  • Oncology