The Overall Reaction Concept in Premixed, Laminar, Steady-State Flames. I. Stoichiometries.

Abstract

Combustion processes normally involve a large number of chemical species, related through a complicated reaction network and strongly interacting with the fluid flow and molecular transport. A common approach is to simplify the system by assuming a single overall or global reaction. In this paper, we will examine the adequacy of the overall reaction model for premixed, laminar, one-dimensional, steady-state flames. Our procedure is to first solve the equations governing the detailed chemistry model. The overall reaction rate parameters are then found from a least squares fit of the heat release profile. The overall reaction model equation can then be solved and the solution compared with the detailed model solution. This is done for three different flames over a range of stoichiometries. The single reaction model gives quite accurate results for flame speed. The temperature and heat release profiles are also generally accurate. The accuracy of the major species profiles varies from fair to good. However, the optimal overall kinetic parameters do vary with stoichiometry.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1983
Accession Number
ADA134738

Entities

People

  • A. J. Kotlar
  • M. S. Miller
  • T. P. Coffee

Organizations

  • Ballistic Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Accuracy
  • Burning Rate
  • Chemical Engineering
  • Chemical Kinetics
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Commerce
  • Engineering
  • Equations
  • Fluid Flow
  • Heat Of Activation
  • Jet Propulsion
  • Mechanical Engineering
  • Military Research
  • Steady State
  • Temperature Gradients

Readers

  • Combustion science or combustion engineering.
  • Computational Modeling and Simulation
  • Finite Element Method (FEM) for solving Partial Differential Equations (PDEs)