Chloride Ion Conductivity in a Plasticized Quaternary Ammonium Polymer.

Abstract

Chloride ion conductivity in anhydrous, plasticized, quaternary ammonium polymer solid electrolytes is studied. Curved plots of 1n(sigma T) vs. 1/T indicate that transport of ions in these materials may be described by WLF-type equations. AC complex impedance measurements for the ranges 5 Hz-500 kHz and 26-98 C with ion-blocking Pt electrodes and ion-reversible calomel electrodes show that the chloride ion is mobile. Conductivities measured range from 7 x .001 to 3 x 10 to the minus 4th power/ohms/cm depending on the plasticizer level and temperature.

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Document Details

Document Type
Technical Report
Publication Date
Nov 22, 1983
Accession Number
ADA135373

Entities

People

  • D. F. Shriver
  • L. C. Hardy

Organizations

  • Northwestern University

Tags

Communities of Interest

  • Advanced Electronics
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkali Metals
  • Alkenes
  • Chemical Engineering
  • Chemical Synthesis
  • Chemistry
  • Dielectric Permittivity
  • Electrolytes
  • Engineering
  • Films
  • Jet Propulsion
  • Materials
  • Materials Science
  • Military Research
  • New Jersey
  • New York
  • Organic Chemistry
  • Polymers

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Polymer Science and Engineering.