Binuclear Schiff Base Complexes of m-Xylylenebis(2-(1,3-Propanedi (2-Pyridinealdmine))) and M-Xylylenebis(2-(1,3-Propanedi(2-Pyrrolealdmine))).

Abstract

Binulcear complexes of Ni, Cu, and Co have been synthesized and characterized. The reaction of nickel(II)-, copper (II)-, or cobalt(II)chloride with a solution of 2-pyridinealdehyde and m-xylylenebis(2-(2,3-propanediamine) results in the formation of Ni2LC14(2a), Cu2LC14 (3) and Co2LC14(4), respectively, where L = m-xylylenebis(2-(2,3-propanedi(2-pyridinealdimine))). The binuclear nickel complexes, Ni2L(N3)4 (2b) and Ni2L(SCN)4 (2c) are prepared by metathesis of the chloride ion of complex 2a using the appropriate sodium salt. These complexes, 2-4, exhibit electronic spectra consistent with tetragonally distorted six-coordinate complexes.

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Document Details

Document Type
Technical Report
Publication Date
Nov 04, 1983
Accession Number
ADA135507

Entities

People

  • B. C. Whitmore
  • R. Eisenberg

Organizations

  • University of Rochester

Tags

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chemistry
  • Chlorides
  • Governments
  • Imines
  • Inorganic Chemistry
  • Military Research
  • New York
  • United States
  • United States Government

Fields of Study

  • Chemistry

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  • Organic Chemistry

Technology Areas

  • Microelectronics