The Chemical Characteristics of PGBx.

Abstract

It was first attempted to separate PGBx, a biologically active material obtained upon alkali treatment of 15-keto-prostaglandin-B1(1), into its components, determine their molecular weight and, finally, molecular structure. When it became clear that PGBx is too complex a mixture, model studies were begun. To investigate the mechanism by which the chemically active moiety in 15-keto-prostaglandin-B1 oligomerizes to PGBx under alkaline conditions, the condensation of 3-ethyl-4-(3'-ketopenten-1-yl) cyclopent-2-enone (2) was investigated.

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Document Details

Document Type
Technical Report
Publication Date
Aug 18, 1983
Accession Number
ADA135851

Entities

People

  • K. Biemann

Organizations

  • Massachusetts Institute of Technology

Tags

DTIC Thesaurus Topics

  • Chemistry
  • Chromatographs
  • Chromatography
  • Complex Mixtures
  • Condensation
  • Desorption
  • Gas Chromatography
  • High Pressure
  • Liquid Chromatography
  • Mass Spectrometry
  • Massachusetts
  • Molecular Structure
  • Molecular Weight
  • Oligomers
  • Prostaglandin
  • Spectrometry

Fields of Study

  • Chemistry

Readers

  • Molecular and Cellular Biochemistry