Polymerization of Functionalized Acetylenes.

Abstract

The initiator that has most frequently been used to metathesize functionalized olefins---WCl6 + (CH3)4Sn---is an effective initiator for the polymerizations of acetylenes substituted by cyano, ester, and halogen groups. Various initiators effective for acetylenic hydrocarbons fail with these funtionalized derivatives. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 09, 1983
Accession Number
ADA137120

Entities

People

  • T. H. Ho
  • T. J. Katz

Organizations

  • Columbia University

Tags

DTIC Thesaurus Topics

  • Acetylenes
  • Acyclic Hydrocarbons
  • Alkynes
  • Chemical Compounds
  • Explosives Initiators
  • Hydrocarbons
  • Organic Compounds
  • Polymerization

Fields of Study

  • Chemistry

Readers

  • Polymer Science and Technology