Detailed Kinetic Studies of Excited and/or Transient Species.

Abstract

Subsequent to the pulsed photolytic (193 nm) production of O(3P) in the presence of CF3I, rapid consecutive reactions lead to the production of IF(X1 sigma 3). All of our measurements are consistent with IF being produced via the reactions: O + CF3I yields OI + CF3 yields F2CO + F, and F + CF3I yields IF + CF3. This route can be quite efficient, and we estimate that > 10% of the O(3P) atoms can lead to IF molecules under suitable conditions.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1984
Accession Number
ADA137278

Entities

People

  • C. Wittig

Organizations

  • University of Southern California

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Atoms
  • Chemical Properties
  • Chemical Reactions
  • Detection
  • Detectors
  • Dye Lasers
  • Laser Induced Fluorescence
  • Lasers
  • Liquid Dye Lasers
  • Measurement
  • Molecules
  • Photolysis
  • Radiation
  • Spectra
  • Spectroscopy

Readers

  • Analytical Mechanics
  • Critical Infrastructure Protection in CBRN and WMD Threats.
  • Molecular Photonics/Laser Physics