Effects of Iodination on the Electrical Conductivity of Hydrogen Bis(Phthalocyaninato) Neodymium(III).

Abstract

Iodination of metallomacrocycles has been shown to be an effective synthetic approach to low-dimensional conducting materials consisting of partially oxidized molecular stacks. The weakness of this approach is that there is little synthetic control over the small differences in molecular and lattice forces which control the formation of stacks. An improvement to this approach was provided by the 'face-to-face' orientation of macrocycles found in the (M(Pc)O) subscript n materials. In this paper we show that a similar orientational effect exists in the linear chain compound composed of stacked hydrogen bis(phthalocyaninato) neodymium(III) (bis(Pc)Nd(III)) sandwich molecules.

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Document Details

Document Type
Technical Report
Publication Date
Jan 25, 1984
Accession Number
ADA137561

Entities

People

  • L. W. Ter Haar
  • M. Tsutsui
  • W. E. Hatfield

Organizations

  • University of North Carolina at Chapel Hill

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Abstracts
  • California
  • Charge Carriers
  • Chemical Reactions
  • Chemistry
  • Electrical Conductivity
  • Heat Of Activation
  • Iodination
  • Iodine
  • Materials
  • Military Research
  • Molecules
  • Neodymium
  • New York
  • North Carolina
  • United States
  • Universities

Readers

  • Materials Science and Engineering.
  • Organic Chemistry
  • Organizational Process Management (OPM).