Surface Ignition and Heterogeneous Catalysis of Hydrocarbon Fuels.

Abstract

This work shows theoredically and experimentally that catalytic combustion is a viable concept at time scales characteristics of those in an engine. A transient code has been developed for hydrogen and carbon monoxide code over a flat plate. Results show that ignition can occur in a time as short as .0001 sec at reasonable temperatures. General operating regions for ignition as a function of the fundamental variables are developed. Radiation heat transfer was also found to be important. Experiments were done for hydrogen combustion over a flat plate were completed which verify the trends seen above. In addition several unexpected phenomenon were observed including self sustained oscillations and isothermal multiplicity and modeled. A detailed kinetic model for formaldehyde combustion has been developed. The main conclusion from the above studies is that catalytic combustion is a complicated process, but it's a viable concept under time scales characteristics of those in an engine. (Author)

Document Details

Document Type
Technical Report
Publication Date
Oct 25, 1983
Accession Number
ADA138214

Entities

People

  • R. I. Masel
  • R. O. Buckius

Organizations

  • University of Illinois Urbana–Champaign

Tags

DTIC Thesaurus Topics

  • Carbon Monoxide
  • Catalysis
  • Chemical Compounds
  • Chemical Reactions
  • Combustion
  • Dielectric Gases
  • Formaldehyde
  • Heat Transfer
  • Hydrocarbon Fuels
  • Hydrocarbons
  • Hydrogen
  • Ignition
  • Materials
  • Monoxides
  • Oscillation

Readers

  • Combustion and Flow Dynamics.
  • Combustion science or combustion engineering.
  • Computational Fluid Dynamics (CFD)