Gas-Liquid Correlation of Ionization Energies.

Abstract

Ionization potentials of ions and molecules are correlated with the threshold energies of their aqueous solutions for photoelectron emission. Inner- and outer-sphere reorganizations are treated, respectively, in terms of a discrete number of dipoles and a continuous medium model. Calculated and experimental threshold energies are compared for halides and hydroxide ions and water. The threshold and reorganization energies of the hydrated electron are calculated from threshold energies of anions and their absorption spectra for charge transfer to the solvent. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1984
Accession Number
ADA141255

Entities

People

  • A. Dziedzic
  • Paul Delahay

Organizations

  • New York University

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption Spectra
  • Aqueous Solutions
  • Charge Transfer
  • Chemical Engineering
  • Chemistry
  • Engineering
  • Engineers
  • Free Energy
  • Ionization Potentials
  • Jet Propulsion
  • Liquids
  • Materials
  • Materials Science
  • Military Research
  • New Jersey
  • New York
  • Polyethylenes

Fields of Study

  • Chemistry
  • Physics

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Electrochemical Surface Science
  • Plasma Physics.

Technology Areas

  • Microelectronics