A Twisted P-C Double Bond: Synthesis and Structure of a (Methylene)phosphine Fe(C0)4 Complex.

Abstract

The reaction of (Me3Si)2C=PCl with LIN(SiMe3)2 affords the tetrasilylated amino(methylene)phosphine 1 which, reacts smoothly with Fe2(CO)9 yielding the eta super 1 complex (Me3Si)2C=P(Fe(CO)4)-N(SiMe3)2 (2). X-ray crystallographic analysis of 2 reveals an unusual coordination of the phosphine ligand in an equatorial position as well as a short (1,657 A), but severely twisted (30.3 deg), P = C double bond. (Author)

Open PDF

Document Details

Document Type
Technical Report
Publication Date
May 18, 1984
Accession Number
ADA141502

Entities

People

  • I. Vickovic
  • R. H. Neilson
  • R. J. Thoma
  • W. H. Watson

Organizations

  • Texas Christian University

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Compounds
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Christianity
  • Methylenes
  • Military Research
  • Organic Chemistry
  • Organophosphorus Compounds
  • Phosphine
  • Phosphorus Compounds
  • Security
  • Spectra
  • United States Government
  • Universities
  • X Rays

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Superconducting Magnet Technology