Raman Investigation of the Rate of OH Uptake in Stressed and Unstressed Optical Fibers

Abstract

Raman measurements of the rate of OH uptake in silicone-clad pure fused silica optical filters (530 ppm initial OH), immersed in water at room temperature, were accomplished with and without tensile stress by determining the integrated intensity of the OH-stretching contour at approx. 3690 per cm. Up to tensile stresses of 1.56 GPa (15.6 kbar), no significant changes in the rate of OH uptake, relative to the uptake rate for an unstressed fiber, were observed. For diffusion through silicone rubber, a 14% increase in the overall Raman OH signal from the fused silica occurred in 200 h. This 14% increase means that a large increase in the OH concentration occurred within a few microns from the surface of the 200 micron diameter fiber, because diffusion of water is very slow in fused silica at room temperature. (Author)

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Document Details

Document Type
Technical Report
Publication Date
May 24, 1984
Accession Number
ADA143142

Entities

People

  • D. R. Hardison Jr
  • G. E. Walrafen
  • P. N. Krishnan

Organizations

  • Howard University

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Argon Lasers
  • Chemistry
  • Coefficients
  • Diffusion
  • Diffusion Coefficient
  • Fibers
  • High Energy
  • Lasers
  • Measurement
  • Optical Fibers
  • Optical Materials
  • Radiation
  • Raman Scattering
  • Raman Spectra
  • Scattering
  • Tensile Stress
  • Universities

Readers

  • Mechanical Engineering/Mechanics of Materials.
  • Spectroscopy.
  • Surface Coatings Technology.