Raman and Infrared Spectroscopy of Molecules Adsorbed on Metal Electrodes.
Abstract
The use of Raman and infrared spectroscopy to obtain the vibrational spectra of molecules and ions adsorbed at the metal electrode-aqueous electrolyte interface are described. To obtain Raman spectra, we use surface polaritons and roughness to enhanced spectral intensities. In the infrared, we use Fourier transform and modulated reflection-absorption techniques. Raman results for fatty acids, chloride, and thiocyanate on silver electrodes are presented, together with a combined Raman and infrared study of cyanide adsorbed on silver. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 01, 1984
- Accession Number
- ADA143466
Entities
People
- H. Seki
- K. Kunimatsu
- M. R. Philpott
- R. Corn
- W. G. Golden
Organizations
- International Business Machines Corporation (Armonk, NY)