High Temperature Oxidation Resistant Coatings

Abstract

The feasibility of chemically vapor depositing hafnium oxide and zirconium oxide onto rhenium substrates as potential oxidation resistant materials was investigated. Deposition of the oxide directly is not feasible on materials which oxidize rapidly since direct deposition requires subjecting these materials to an oxidizing environment prior to deposition. Deposition of the oxide was accomplished by first depositing the metal carbide and then oxidizing it. Hard, dense continuous coatings of hafnium carbide which showed good bond strength were achieved. Post coating heat treatment results in a good metallurgical bond between the carbide and the substrate. It has been demonstrated that hafnium carbide/oxide is orders-of-magnitude more oxidation resistant that rhenium or tungsten. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1984
Accession Number
ADA143633

Entities

People

  • J. T. Harding
  • R. B. Kaplan
  • R. H. Tuffias

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemical Vapor Deposition
  • Chemistry
  • Coatings
  • Heat Treatment
  • High Temperature
  • Materials
  • Metal Oxides
  • Oxidation
  • Oxidation Resistance
  • Oxides
  • Refractory Materials
  • Resistance
  • Rocket Engines
  • Rocket Propulsion
  • Rockets
  • Zirconium Oxides

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science and Engineering.
  • Semiconductor Device Technology