Kinetics of Simple Inner- and Outer-Sphere Electrochemical Reactions at Rotating Silver Electrodes as Examined Using Surface-Enhanced Raman Spectroscopy.
Abstract
An application of surface-enhanced Raman spectroscopy (SERS) to evaluating the kinetics of electrochemical reactions is outlined. This involves monitoring the potential-dependent SERS intensities of the adsorbed reactant at a rotating disk electrode in a potential region where the kinetics are under mixed mass transfer-heterogeneous electron transfer control. Comparisons are made between the kinetic behavior extracted from the SERS intensity-potential dependence and that obtained from the faradaic current flow.
Document Details
- Document Type
- Technical Report
- Publication Date
- Sep 01, 1984
- Accession Number
- ADA145606
Entities
People
- D. Milner
- M. A. Tadayyoni
- Michael J. Weaver
- Stuart Farquharson
Organizations
- Purdue University