Solvent Effects upon Electrochemical Kinetics: Influences of Interfacial Solvation and Solvent Relaxation Dynamics.

Abstract

This paper is intended as a summary of some recent research aimed at gaining a fundamental understanding of solvent effects in electrochemical kinetics. Besides examining the effects of altering the bulk solvent, experiments are also described where the influence of the interfacial solvent structure in aqueous media is probed through variations in the hydrophility of the metal surface. Particularly since some of this recent experimental activity has been associated closely with concurrent theoretical development, it is useful to provide a brief summary of the underlying kinetic formulations.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1984
Accession Number
ADA145624

Entities

People

  • Michael J. Weaver

Organizations

  • Purdue University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Carbonate Esters
  • Chemical Engineering
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Dynamics
  • Electrochemical Kinetics
  • Electrochemical Reactions
  • Electrochemistry
  • Electrodes
  • Electron Transfer
  • Free Energy
  • Frequency
  • Hydrophilic Properties
  • Kinetics
  • Molecular Dynamics
  • Organic Chemistry

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Theoretical Analysis.