Synthesis of Stereoisomeric - Metal Complexes Using Phase-Transfer Catalysis and Photochemical Transforms.
Abstract
Cyclopentadienyl carbonyl complexes of iron and ruthenium have been shown to have broad applications in organic synthesis. The viability of these complexes as intermediates is dependent upon convenient and rapid synthetic routes for their preparation. This research has primarily been directed towards the extension of phase-transfer techniques to the preparation of iron and ruthenium allyl and crotyl complexes. In addition, the synthesis of iron and ruthenium olefin complexes by photochemical techniques has been investigated.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 25, 1984
- Accession Number
- ADA145787
Entities
People
- D. J. Brown
Organizations
- United States Naval Academy