Computer Molecular Dynamics of 2-D Water (Ice) Structures under Shock.

Abstract

Computer molecular dynamics has been used to study the shock-front transition region for a series of two-dimensional hydrogen-bonded structures composed of water-vapor molecules. Two different structures were examined and different intermolecular potential were considered. Sample sizes and running times were chosen to correspond to the predicted shock-front rise-time in real water. In this way the effect of different potentials and initial structures on the equilibration associated with the shock-front transition in water could be investigated. In addition to studying the development and incipient relaxation of shock-polarization states, we have also considered the propagation and possible incipient relaxation of structural phase transitions occuring in two-dimensional structures. The results of these molecular dynamics calculations are compared with the experimental shock behavior of real water; in particular, comparisons are made with respect to intermolecular hydrogen-bond breaking, dissociation, and dissociation-related electrical conductivity data.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1984
Accession Number
ADA145818

Entities

People

  • A. M. Karo
  • P. Harris

Organizations

  • Lawrence Livermore National Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemistry
  • Computational Science
  • Computers
  • Conductivity
  • Dissociation
  • Dynamics
  • Electrical Conductivity
  • Equations
  • Frequency
  • Hydrogen Bonds
  • Molecular Dynamics
  • Phase Transformations
  • Picosecond Time
  • Polarization
  • Shock Waves
  • Two Dimensional
  • Water Vapor

Fields of Study

  • Physics

Readers

  • Combustion and Flow Dynamics.
  • Combustion science or combustion engineering.
  • Quantum Chemistry